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I sent a request to Starz, but no reply as of yet. Watching Starz Encore Westerns, I DVR all the Maverick episodes. Right before the start of Maverick, they show a number of movie clips and the song goes like this

"Dark Horse, renegade, vigilante - they call me an outlaw"

I have been searching the internet without any success for weeks now. Anyone have any information on the ad song?